68 photos of Angelina Jolie and Brad Pitt's most stunning looks

The Brangelina divorce may be getting ugly, but these two beautiful A-list stars always were gorgeous on the red carpet together. 

From their first to their last red carpet appearance, keep scrolling to see their most iconic looks.

2005: Their first red carpet appearance was for "Mr. & Mrs. Smith."

Jolie wore a leather dress while Pitt had super blonde hair and a leather jacket. As though to fight the rumors of an on-set affair, producer Arnon Milchan stood between them.

2006: Their next red carpet look was after the birth of their daughter, Shiloh Jolie-Pitt.

They were officially an item by the red carpet world premiere of Jolie's movie, "The Good Shepherd."

2007: Brangelina was ready for prom at the Golden Globes.

2007: They looked Old Hollywood-glam at Cannes.

2007: Angelina chose a vibrant color for the "Ocean's Thirteen" premiere.

2007: Another one of Brangelina's many all-black looks for a different "Ocean's Thirteen" premiere.

2007: And another one, this time for Jolie's movie, "A Mighty Heart."

2007: Angie wore pearls and Brad wore white at the Venice Film Festival.

2007: Matching again in shiny shirts and suits at "The Assassination of Jesse James."

2007: Looking seriously grey-t at the Toronto International Film Festival.

2007: All black everything at another "Jessie James" screening.

2007: Angelina had strong coat game, but Brad needed different shoes at the "Beowulf" premiere.

2007: At "Beowulf" again, the couple wore all black ensembles.

2008: Brad's little scarf cracks me up at the Critics' Choice Awards.

2008: Angelina was a watercolored Earth goddess at the Screen Actors Guild awards.

2008: Angelina premiered her new baby bump at the Film Independent's Spirit Awards.

2008: Pregnant with twins Knox and Vivienne, Angelina looked fabulous at Cannes.

2008: Another one from Cannes. See what I mean?

2008: "Do you want to wear black, or should I?" Brad and Angelina can't decide at the "Changeling" premiere.

2008: Brad rocks a mini mustache at "The Curious Case Of Benjamin Button."

2009: Angelina looks like a living statue at the Critics' Choice Awards.

2009: Angelina's dress was so sparkly Brad needed sunglasses at the Golden Globes.

2009: Brad and Angelina laugh at us lesser mortals at the German premiere of "The Curious Case of Benjamin Button."

2009: For the Paris premiere, they wore matching grey slacks.

2009: Brad tried to match his pocket square to Angie's dress at the Screen Actors Guild Awards.

2009: They know they killed it at the Orange British Academy Film Awards.

2009: Angelina allowed her stylist a pop of color in her jewelry at the Oscars.

2009: Only Angelina and her red lipstick could make a flesh-colored dress look so good at Cannes.

2009: Lookin' badass at the "Inglourious Basterds" premiere. Wowza.

2010: They're both ready for the party at the premiere of "Salt."

2010: Wearing black in all types of textures at the "Megamind" Paris premiere.

2010: Proving that even when you're cold, you can look classy at the world premiere of "The Tourist."

2010: Shiny pants? Check. Hat and scarf? Check. Classic Brangelina at "The Tourist" Italy premiere.

2010: Both of them went for bottoms with a bit of sheen at "The Tourist" Madrid premiere.

2011: Iconic. Brangelina slayed the Golden Globes this year.

2011: The couple went for different colors at Cannes — chocolate and navy!

2011: Angelina looked amazing at the "Kung Fu Panda 2" premiere. Brad looked questionable.

2011: More sunglasses at "The Tree of Life" premiere.

2011: And even more sunglasses at the "Moneyball" premiere!

2011: Brad just loves wearing glasses on the red carpet. Here he is at the Tokyo premiere of "Moneyball."

2011: Angelina looks regal at the premiere of "In the Land of Blood and Honey."

2011: At a different "Blood and Honey" premiere, she looked like she was going to prom.

2012: Brad needed a cane at the Palm Springs International Film Festival Awards Gala.

2011: And again at the New York Film Critics Circle awards.

2012: Angelina is breathtaking at the Golden Globes. There's Brad with that cane again.

2012: Brad's hair is getting super long at the Producers Guild Awards.

2012: They both had slicked back hair at the Screen Actors Guild Awards.

2012: Brad is suitably in awe of Angelina at the Berlin International Film Festival.

2012: Angelina looks beautiful and professional at the Cinema for Peace Gala. Brad looks ... fine.

2012: Angie makes quite the shoulder statement at the "In the Land Of Blood And Honey" Paris premiere.

2012: The leg!! Angelina's leg pop at the 84th Annual Academy Awards became a viral sensation.

2013: More black at the world premiere of "World War Z."

2013: And even more black at the Paris premiere!

2013: Angelina looks like she stepped out of the year 2200 in this futuristic dress at the Germany premiere. Brad looks tired.

2013: It was back to black for the Tokyo premiere of "World War Z." Look at how long Brad's hair is!

2013: Maddox joined the stars on the red carpet at the Academy of Motion Picture Arts and Sciences' Governors Awards. So long to Brad's long locks!

2014: Angelina looked better than Brad in a suit at the EE British Academy Film Awards.

2014: They really turned up the glam for the Oscars.

2014: Cheekbones galore at the "Maleficent" costumes and props exhibit.

2014: The shoes, the dress, the makeup on her left cheek ... Angelina has looked better at "The Normal Heart" New York premiere.

2014: Angie wore a questionable pleather gown to the world premiere of "Maleficient."

2014: She looked ready for the four-day conference on sexual violence in and out of war at the Global Summit to End Sexual Violence in Conflict.

2014: Japanese singers Melody and Miyavi Ishihara stood between them at the world premiere of "Unbroken."

2015: The duo were looking very casual chic at the Annual AFI Awards.

2015: Angelina looks demure at the official Academy Screening for "By the Sea." Brad's rocking his classic hat-and-tie combo.

2015: They bestowed one last classic black look on us at the WSJ Magazine 2015 Innovator Awards.

2015: And here it is — their last red carpet appearance at the opening night gala premiere for "By the Sea," nearly a year ago.

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